Ø Review Articles:

07. M. Shieh* and C.-N. Lin, “Chromium- and Manganese-containing Carbonyl Chalcogenide Clusters: Syntheses, Reactivities, and Special Properties, J. Chin. Chem. Soc. 2014, 61, 187.---Special Issue for the 60th Anniversary of Journal of the Chinese Chemical Society. [10.1002/jccs.201300379]

06. M. Shieh,* C.-Y. Miu, Y.-Y. Chu and C.-N. Lin, Recent Progress in the Chemistry of Anionic Groups 6–8 Carbonyl Chalcogenide Clusters Coord. Chem. Rev. 2012, 256, 637. [10.1016/j.ccr.2011.11.010]

05. M. Shieh* and C.-Y. Miu, Carbonylchromium Chalcogenide Complexes: Synthesis, Reactivity and Properties, J. Chin. Chem. Soc. 2010, 57, 956. [10.1002/jccs.201000133]

04. M. Shieh* and M.-H. Hsu, Chalcogen-Containing Manganese Carbonyl Clusters: Synthesis and Structural Transformations, J. Cluster Sci. 2004, 15, 91. [10.1023/B:JOCL.0000027395.39228.01]

03. M. Shieh* and Y.-W. Lai, “Chalcogen-Bridging Iron Carbonyl Complexes: Cluster Growth and Reactivity Comparsion, J. Chin. Chem. Soc. 2002, 49, 851. [10.1002/jccs.200200121]

02. M. Shieh,* Recent Developments of Tellurium-and Selenium-Containing Iron Carbonyl Clusters, J. Cluster Sci. 1999, 10, 3. [10.1023/A:1022648516747]

01. M. Shieh* and Y.-C. Tsai, Bridge between Main Group Element and Transition Metal Carbonyl Cluster, Chemistry 1993, 51, 234.

Ø Journal Papers:

48. M. Shieh,* Y.-Y. Chu, L.-F. Jang and C.-H. Ho, “CO and CO2 Fixation by Se─Ru─CO Hydride Clusters,” Inorg. Chem. 2014, 53, 4284. [10.1021/ic500821z]

47. C.-N. Lin, W.-T. Jhu and M. Shieh,* “Vapochemically and Mechanochemically Reversible Polymerization/Depolymerization of S─Fe─Cu Carbonyl Clusters,” Chem. Commun. 2014, 50, 1134. [10.1039/c3cc48303g]

46. M. Shieh,* Y.-Y. Chu, H.-H. Chi, H.-S. Chen, K.-J. Hsing and C.-Y. Huang,Reactions of Iron Acyl Chalcogenide Clusters with Electrophiles: Reactivity Comparison and Theoretical Calculations, J. Chin. Chem. Soc. 2013, 60, 725. [10.1002/jccs.201200553]

45. M. Shieh,* C.-H. Yu, Y.-Y. Chu, Y.-W. Guo, C.-Y. Huang, K.-J. Hsing, P.-C. Chen and C.-F. Lee, “Trigonal-Bipyramidal and Square-Pyramidal Chromium–Manganese Chalcogenide Clusters, [E2CrMn2(CO)n]2– (E = S, Se, Te; n = 9, 10): Synthesis, Electrochemistry, UV/Vis Absorption, and Computational Studies,“ Chem. Asian. J. 2013, 8, 963. [10.1002/asia.201201163]

44. M. Shieh,* C.-Y. Huang, C.-J. Lee, K.-J. Hsing, Y.-W. Li, Y.-Y. Chu and W.-T. Jhu, Controlled Synthesis of Copper Halide-Incorporated Triiron Carbonyl Sulfide Clusters: Synthesis, Electrochemistry, and Computational Studies, Polyhedron 2013, 52, 879. [10.1016/j.poly.2012.07.026]

43. M. Shieh,* C.-Y. Miu, K.-C. Huang, C.-F. Lee and B.-G. Chen, “Stepwise Construction of Manganese-Chromium Carbonyl Chalcogenide Complexes: Synthesis, Electrochemical Properties, and Computational Studies,” Inorg. Chem. 2011, 50, 7735. [10.1021/ic200885h]

42. C.-Y. Miu, H.-H. Chi, S.-W. Chen, J.-J. Cherng, M.-H. Hsu, Y.-X. Huang  and M. Shieh,* “Reactions of the m3-Sulfido Triiron Cluster [SFe3(CO)9]2- with Functionalized Organic Halides and Mercury Salts: Selective Reactivity, Electrochemistry, and Theoretical Calculations,”  New J. Chem. 2011, 35, 2442. [10.1039/c1nj20279k]

41. M. Shieh,* Y.-Y. Chu, M.-H. Hsu, W.-M. Ke and C.-N. Lin, “Lead-Chromium Carbonyl Complexes Incorporated with Group 8 Metals: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem. 2011, 50, 565. [10.1021/ic101560u]

40. C.-H. Ho, Y.-Y. Chu, C.-N. Lin, H.-W. Chen, C.-Y. Huang and M. Shieh,* Selenium−Manganese Carbonyl Clusters: Synthesis, Reversible Transformation, Electrochemical Properties, and Theoretical Calculations, Organometallics 2010, 29, 4396. [10.1021/om1006819]

39. M. Shieh,* C.-N. Lin, C.-Y. Miu, M.-H. Hsu, Y.-W. Pan and L.-F. Ho, “Chromium-Manganese Selenide Carbonyl Complexes: Paramagnetic Clusters and Relevance to C=O Activation of Acetone,” Inorg. Chem. 2010, 49, 8056. [10.1021/ic101118y]

38. M. Shieh,* C.-H. Ho, W.-S. Sheu* and H.-W. Chen, “Selective Insertion of Oxygen and Selenium into an Electron-Precise Paramagnetic Selenium-Manganese Carbonyl Cluster [Se6Mn6(CO)18]4-,” J. Am. Chem. Soc. 2010, 132, 4032. [10.1021/ja9091566]

37. M. Shieh,* Y.-Y. Chu, C.-Y. Miu, P.-F. Wu and T.-M. Zeng, Bimetallic Ru-Cu Tellurido Complexes: Controlled Synthesis and Electrochemical Studies of Copper Halide-TeRu5 and Te2Ru4 Clusters, Dalton Trans. 2010, 39, 1492. (Selected as a Hot Article) [10.1039/b919176c]

36. B.-G. Chen,  C.-H. Ho, C.-J. Lee and M. Shieh,* “Copper Halide-Incorporated Tellurium-Iron Carbonyl Complexes: Transformation, Electrochemical Properties, and Theoretical Calculations,” Inorg. Chem. 2009, 48, 10757. [10.1021/ic901647n]

35. M. Shieh,* C.-H. Ho, W.-S. Sheu*, B.-G. Chen, Y.-Y. Chu, C.-Y. Miu, H.-L. Liu and C.-C. Shen, “Semiconducting Tellurium–Iron–Copper Carbonyl Polymers,” J. Am. Chem. Soc. 2008, 130, 14114. [10.1021/ja8065623]

34. M. Shieh,* C.-Y. Miu, C.-J. Lee, W.-C. Chen, Y.-Y. Chu and H.-L. Chen, “Construction of Copper Halide-Triiron Selenide Carbonyl Complexes: Synthetic, Electrochemical, and Theoretical Studies,” Inorg. Chem. 2008, 47, 11018. [10.1021/ic8012552]

33. M. Shieh,* L.-F. Ho, P.-C. Chen, M.-H. Hsu, H.-L. Chen, Y.-W. Guo, Y.-W. Pan and Y.-C. Lin, “Reaction of [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3) toward Electrophiles: Reactivity Comparison and Theoretical Calculations,” Organometallics 2007, 26, 6184. [10.1021/om700789a]

32. M. Shieh,* M.-H. Hsu, W.-S. Sheu, L.-F. Jang, S.-F. Lin, Y.-Y. Chu, C.-Y. Miu, Y.-W. Lai, H.-L. Liu and J.-L. Her, A New Series of Copper Halide-Bridged Ruthenium Telluride Carbonyl Complexes: Discovery of a Unique Semiconducting Cluster Chain Polymer [{PPh4}2{Te2Ru4(CO)10Cu4Br2Cl2}·THF]¥, Chem. Eur. J. 2007, 13, 6605. [10.1002/chem.200700135]

31. M.-H. Hsu, R.-T. Chen, W.-S. Sheu and M. Shieh,* Carbon Dioxide Fixation by an Unprecedented Hydroxo Lead-Chromium Carbonyl Complex: Synthesis, Reactivity, and Theoretical Calculations, Inorg. Chem. 2006, 45, 6740. [10.1021/ic060554o]

30. M.-H. Hsu, C.-Y. Miu, Y.-C. Lin and M. Shieh,* Selenium-Capped Trimolybdenum and Tritungsten Carbonyl Clusters [Se2M3(CO)10]2- (M = Mo, W), J. Organomet. Chem. 2006, 691, 966. [10.1016/j.jorganchem.2005.10.039]

29. Y.-W. Lai, J.-J. Cherng, W.-S. Sheu, G.-A. Lee and M. Shieh,* Novel Types of Organic S-Fe-CO Complexes: Reaction of [SFe3(CO)9]2- with Propargyl Bromide, Organometallics 2006, 25, 184. [10.1021/om050694q]

28. M. Shieh* and C.-H. Ho, Reactivities of the Chalcogen-Capped Triiron Clusters [EFe3(CO)9]2- (E = Te, Se, S): Cluster Growth and Transformations, C. R. Chimie 2005, 8, 1838. [10.1016/j.crci.2005.03.014]

27. M. Shieh,* S.-F. Lin, Y.-W. Guo, M.-H. Hsu and Y.-W. Lai, New Strategy to Mixed-Group 6 Metal Carbonyl Telluride Complexes: Completion of the Trigonal Bipyramidal Clusters [Te2CrM2(CO)10]2- (M = Cr, Mo, W), Organometallics 2004, 23, 5182. [10.1021/om049515f]

26. M. Shieh,* H.-S. Chen and Y.-W. Lai, “Reaction of the Tellurium-Capped Triiron Cluster [TeFe3(CO)9]2- with the Bifunctional Propargyl Bromide: Formation of a Series of Novel Organic Te-Fe-CO Complexes, Organometallics 2004, 23, 4018. [10.1021/om049712e]

25. M. Shieh,* L.-F. Ho, Y.-W. Guo, S.-F. Lin, Y.-C. Lin, S.-M. Peng and Y.-H. Liu, Carbonylchromium Monotelluride Complexes [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3): Two Important Intermediates, Organometallics 2003, 22, 5020. [10.1021/om034033+]

24. M. Shieh,* R.-L. Chung, C.-H. Yu, M.-H Hsu, C.-H. Ho, S.-M. Peng and Y.-H. Liu, “The Unusual Paramagnetic Mixed-Metal Carbonyl Chalcogenide Clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se), Inorg. Chem. 2003, 42, 5477. [10.1021/ic034081m]

23. M. Shieh,* J.-J. Cherng, Y.-W. Lai, S.-M. Peng and Y.-H. Liu, “Carbonylchromium Derivatives of Bismuth: New Syntheses and Relevance to C-O Activation, Chem. Eur. J. 2002, 8, 4522. [10.1002/1521-3765(20021004)8:19<4522::AID-CHEM4522>3.0.CO;2-7]

22. M. Shieh,* Y. Liou, M.-H. Hsu, R.-T. Chen, S.-J. Yeh, S.-M. Peng and G.-H. Lee, A Unique Bismuth-Iron Chain Polymer Containing the ...-Bi-Fe-... Link: Formation and Structure of [n-BuBiFe(CO)4]¥,  Angew. Chem. Int. Ed. Engl. 2002, 41, 2384. [10.1002/1521-3773(20020703)41:13<2384::AID-ANIE2384>3.0.CO;2-#]

21. M. Shieh,* H.-S. Chen, H.-Y. Yang, S.-F. Lin and C.-H. Ueng, “Tellurium-Bridged Manganese Carbonyl Clusters: Synthesis and Structural Transformations of [Te4Mn3(CO)10]-, [Te2Mn3(CO)9]2-, [Te2Mn3(CO)9]-, and [Te2Mn4(CO)12]2-, Chem. Eur. J. 2001, 7, 3152. [10.1002/1521-3765(20010716)7:14<3152::AID-CHEM3152>3.0.CO;2-B]

20. M. Shieh,* L.-F. Ho, L.-F. Jang, C.-H. Ueng, S.-M. Peng and Y.-H. Liu, First Selenium-Capped Carbonyltrichromium Complex [Se2Cr3(CO)10]2-: a Novel Cr3 Ring Cluster, Chem. Commun. 2001, 1014. [10.1039/b101283p]

19.  J.-J. Cherng, Y.-W. Lai, Y.-H. Liu, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis of Chromium Pentacarbonyl Dertives of Arsenic(V) and Antimony(V). Contrasting Chemical Reactivity with Organic Halogen Derivatives, Inorg. Chem. 2001, 40, 1206. [10.1021/ic0004277]

18. M. Shieh,* H.-S. Chen, H.-H Chi and C.-H. Ueng, “Synthesis of an Se-Bridged Triiron Acyl Cluster Complex and the Fischer-Type Carbene Complex Derived from It: Isolation of Rotation Isomers,” Inorg. Chem. 2000, 39, 5561. [10.1021/ic000301+]

17. J.-J. Cherng, G.-H. Lee, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis and Characterization of a New Series of Chromium-Group 15 Hydride Complexes [Et4N]2[H{Cr(CO)5}3]) (E = As, Sb),” Organometallics 2000, 19, 213. [10.1021/om990717z]

16. M. Shieh,* L.-F.Ho, J.-J,Cherng, C.-H. Ueng, G.-H. Lee and S.-M. Peng, “[Et4N]2[MeSb{Fe(CO)4}3] toward HOAc and [Cu(MeCN)4]BF4: Formation of [Et4N][Me(OAc)Sb{Fe(CO)4}2] and [MeSb{Fe(CO)4}{Fe2(CO)8},”  J. Organomet. Chem. 1999, 587, 176. [10.1016/S0022-328X(99)00291-0]

15. M. Shieh,* H.-S. Chen, Y.-H Yang and C.-H. Ueng, “[Mn(CO)4TeMe25-Te)(μ4-Te)Mn4(CO)12]- : A Pentacoordinate Bridging Tellurido Ligand in a Square Pyramidal Geometry,” Angew. Chem. Int. Ed. Engl. 1999, 38, 1252. [10.1002/(SICI)1521-3773(19990503)38:9<1252::AID-ANIE1252>3.0.CO;2-A]

14. K.-C. Huang, M.-H. Shieh, R.-J. Jang, S.-M. Peng, G.-H. Lee and M. Shieh,* “Structural Transformations of a Series of Tellurium-Iron Carbonylates and the Isolation of a Cubic Cluster [Te4Fe4(CO)10(dppm)],” Organometallics 1998, 17, 5202. [10.1021/om980516f]

13. J.-J. Cherng, Y.-C. Tsai, C.-H. Ueng, G.-H. Lee, S.-M. Peng and M. Shieh,* “New Synthesis of [SFe3(CO)9]2- and Its Reactivity toward Electrophiles,” Organometallics 1998, 17, 255. [10.1021/om970710m]

12. K.-C. Huang, Y.-C. Tsai, G.-H, Lee, S.-M. Peng and M. Shieh,* “Syntheses and X-ray Structures of Chalcogen-Containing Manganese Carbonylates [E2Mn3(CO)9]-, [E8C2Mn2(CO)6]2-, and [E2Mn4(CO)12]2- (E = Se, S),” Inorg. Chem. 1997, 36, 4421. [10.1021/ic961482b]

11. M. Shieh,* Y.-C. Tsai, M.-H. Shieh, J.-J. Cherng, H.-S. Chen, C.-H. Ueng, S.-M. Peng and G.-H. Lee, “Reactivity of [SeFe3(CO)9]2- with Some Electrophiles: Formation of [SeFe2Ru3(CO)14]2-, [SeFe3(CO)9(μ-HgI)]-, Fe2(CO)6(μ-SeCHPhSe), and Se2Fe2(CO)6(μ-CH2)2,” Organometallics 1997, 16, 456. [10.1021/om960767t]

10. M. Shieh,* C.-M. Sheu, L.-F. Ho, J.-J. Cherng, L.-F. Jang, C.-H. Ueng, S.-M. Peng and G.-H. Lee, Reaction of [Et4N]3[Sb{Fe(CO)4}4] with Alkyl Halide and Dihalides Formation of the Monoalkyl and the Dialkyl Antimony-Iron Carbonyl Complexes, Inorg.Chem. 1996, 35, 5504. [10.1021/ic9513393]

09. M. Shieh,* M.-H. Shieh, Y.-C. Tsai and C.-H. Ueng, Transformations of Selenium-Iron Carbonylates in Hieber's Synthesis: Isolation of an Intermediate Complex [PhCH2NMe3]2{Se6Fe6(CO)12}, Inorg. Chem. 1995, 34, 5088. [10.1021/ic00124a028]

08. M. Shieh,* T.-F. Tang, S.-M. Peng and G.-H. Lee, Effects on Main-Group and Transition Elements on Bond Formation and Cleavage in Transition-Metal Chalcogenide Clusters: Reactions of E2Fe3(CO)9 (E = Te, Se) with [Co(CO)4]-, [Mn(CO)5]-, and [Fe(CO)4]2-, Inorg. Chem. 1995, 34, 2797. [10.1021/ic00115a004]

07. M. Shieh,* P.-F. Chen, Y.-C. Tsai, M.-H. Shieh, S.-M. Peng and G.-H. Lee, Facile Syntheses and Transformations of a Series of Tellurium-Iron Carbonyl Clusters: Crystal Structures of [PhCH2NMe3]2[Te6Fe8(CO)24], Fe2(CO)6(μ-TeCHCl2)2, and Fe2(CO)6(μ-TeCHPhTe), Inorg. Chem. 1995, 34, 2251. [10.1021/ic00112a043]

06. M. Shieh* and Y.-C. Tsai, Preparation of [SeFe3(CO)9]2- and Its Derivatives[{SeFe3(CO)9}2M]2- (M = Hg, Cd), Inorg. Chem. 1994, 33, 2303. [10.1021/ic00088a037]

05. M. Shieh* and M.-H. Shieh, Reaction of [Te6Fe8(CO)24]2- with Dihaloalkanes: A New Route to Organotellurium Complexes of  Iron, Organometallics 1994, 13, 920. [10.1021/om00015a027]

04. M. Shieh,* Y. Liou and B.-W. Jeng, Reactions of [Et4N]3[Bi{Fe(CO)4}4] with Alkyl Halides and Dihalides: A General Method for the Synthesis of Anionic Complex of Type [Et4N]2[RBi{Fe(CO)4}3] and Cyclic Complexes, R2Bi2Fe2(CO)8, Organometallics 1993, 12, 4926. [10.1021/om00036a036]

03. M. Shieh,* P.-F. Chen, S.-M. Peng and G.-H. Lee, An Unusual Mixed Tellurium-Iron Carbonylate: Synthesis, Structure and Reactivity of [PhCH2NMe3]2[Te6Fe8(CO)24], Inorg. Chem. 1993, 32, 3389. [10.1021/ic00068a001]

02. M. Shieh,* F.-D. Mia, S.-M. Peng and G.-H. Lee, Synthesis and X-ray Crystal Structure of a Tetrahedral Bismuth-Molybdenum Carbonyl Complex Possessing. Three Bridging Methoxy Ligands, [Et4N]2[BiMo4(CO)123-OMe)3]CH2Cl2, Inorg. Chem. 1993, 32, 2785. [10.1021/ic00064a033]

01. M. Shieh,* Y. Liou, S. -M. Peng and G. -H. Lee, Reaction of [Et4N]3[Bi{Fe(CO)4}4] with i-BuBr. Isolation of the Tetrahedral Anionic Complex, [Et4N]2[i-BuBi{Fe(CO)4}3], and the Ring Complex (i-Bu)2Bi2Fe2(CO)8, Inorg. Chem. 1993, 32, 2212. [10.1021/ic00062a055]