:::

個人詳細資料

:::
˹ʹϤ
姓名 Minghuey Shieh
Office_Hour  
實驗室電話 (02)77346187; (02)77346188
辦公室電話 (02)77346118
傳真 (02)29309081
聯絡地址 （11677）No. 88, Sec. 4, Ting-Chow Rd, Taipei, Taiwan, 11677, R.O.C.
E-mail mshieh@ntnu.edu.tw
實驗室網頁 http://www.chem.ntnu.edu.tw/~MShieh/index.html
類別 Full-Time
職稱 Professor
研究領域 Metal Cluster Chemistry, Organometallics, Material Chemistry, Computational Chemistry
學術專長 Major goals of our research include synthetic, magnetic, electrochemical, and theoretical studies of heavier main group elements-containing transition metal carbonyl clusters.
指導學生  
實驗室 Metal Cluster Chemistry Lab /

Academic Researches

  1. Journal Articles
    1. C.-N. Lin, W.-T. Jhu and M. Shieh,* “Vapochemically and Mechanochemically Reversible Polymerization/Depolymerization of S─Fe─Cu Carbonyl Clusters,“ Chem. Commun. 2014, 50, 1134-1136.
    2. M. Shieh,* C.-H. Yu, Y.-Y. Chu, Y.-W. Guo, C.-Y. Huang, K.-J. Hsing, P.-C. Chen and C.-F. Lee, “Trigonal Bipyramidal and Square Pyramidal Chromium─Manganese Chalcogenide Clusters [E2CrMn2(CO)n]2─ (E = S, Se, Te; n = 9, 10): Synthesis, Electrochemistry, UV/Vis Absorption, and Computational Studies,” Chem. Asian J., 2013, 8, 963-973.
    3. M. Shieh,* C.-Y. Huang, C.-J. Lee,K.-J. Hsing, Y.-W. Li, Y.-Y. Chu and W.-T. Jhu, “Controlled Synthesis of Copper Halide-IncorporatedTriiron Carbonyl Sulfide Clusters: Synthesis, Electrochemistry, and Computational Studies,” Polyhedron, 2013, 52, 879-889.
    4. M. Shieh,* C.-Y. Miu, Y.-Y. Chu and C.-N. Lin, “Recent Progress in the Chemistry of Anionic Groups 6─8 Carbonyl Chalcogenide Clusters,” Coord. Chem. Rev., 2012, 256, 637-694.
    5. M. Shieh,* C.-Y. Miu, K.-C. Huang, C.-F. Lee and B.-G. Chen, “Stepwise Construction of Manganese─Chromium Carbonyl Chalcogenide Complexes: Synthesis, Electrochemical Properties, and Computational Studies,” Inorg. Chem., 2011, 50, 7735-7748.
    6. M. Shieh,* Y.-Y. Chu, M.-H. Hsu, W.-M. Ke and C.-N. Lin, “Lead-Chromium Carbonyl Complexes Incorporated with Group 8 Metals: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem., 2011, 50, 565-575.
    7. C.-H. Ho, Y.-Y. Chu, C.-N. Lin, H.-W. Chen, C.-Y. Huang and M. Shieh,* “Selenium─Manganese Carbonyl Clusters: Synthesis, Reversible Transformation, Electrochemical Properties, and Theoretical Calculations,” Organometallics, 2010, 29, 4396-4405.
    8. M.Shieh,* C.-N. Lin, C.-Y. Miu, M.-H. Hsu, Y.-W. Pan and L.-F. Ho, “Chromium-Manganese Selenide Carbonyl Complexes: Paramagnetic Clusters and Relevance to C=O Activation of Acetone,” Inorg. Chem., 2010, 49, 8056-8066.
    9. M. Shieh,* C.-H. Ho,W.-S. Sheu* and H.-W. Chen, “Selective Insertion of Oxygen and Selenium into an Electron-Precise Paramagnetic Selenium─Manganese Carbonyl Cluster [Se6Mn6(CO)18]4−,” J. Am. Chem. Soc., 2010, 132, 4032-4033.
    10. M. Shieh,* Y.-Y. Chu, C.-Y. Miu, P.-F. Wu and T.-M. Zeng, “Bimetallic Ru-Cu Tellurido Complexes: Controlled Synthesis and Electrochemical Studies of Copper Halide-TeRu5 and Te2Ru4 Clusters,”Dalton Trans., 2010, 39, 1492. (Selected as a Hot Article)
    11. B.-G. Chen, C.-H. Ho, C.-J. Lee and M. Shieh,* “Copper Halide-Incorporated Tellurium─Iron Carbonyl Complexes: Transformation, Electrochemical Properties, and Theoretical Calculations,” Inorg. Chem., 2009, 48, 10757-10768.
    12. M. Shieh,* C.-H. Ho, W.-S. Sheu,* B.-G. Chen, Y.-Y. Chu, C.-Y. Miu, H.-L. Liu and C.-C. Shen, “Semiconducting Tellurium–Iron–Copper Carbonyl Polymers,” J. Am. Chem. Soc., 2008, 130, 14114.
    13. M. Shieh,* C.-Y. Miu, C.-J. Lee, W.-C. Chen, Y.-Y. Chu and H.-L. Chen, “Construction of Copper Halide-Triiron Selenide Carbonyl Complexes: Synthetic, Electrochemical, and Theoretical Studies,” Inorg. Chem., 2008, 47, 11018.
    14. M. Shieh,* M.-H. Hsu, W.-S. Sheu, L.-F. Jang, S.-F. Lin, Y.-Y. Chu, C.-Y. Miu, Y.-W. Lai, H.-L. Liu and J. L. Her, “Copper Halide-Bridged Ruthenium Telluride Carbonyl Complexes: Discovery of the Semiconducting Cluster Chain Polymer [{PPh4}2{Te2Ru4(CO)10Cu4Br2Cl2}·THF]¥,” Chem-Eur. J., 2007, 13, 6605.
    15. M. Shieh,* L.-F. Ho, P.-C. Chen, M.-H. Hsu, H.-L. Chen, Y.-W. Guo, Y.-W. Pan and Y.-C. Lin, “Reaction of [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3) toward Electrophiles: Reactivity Comparison and Theoretical Calculations,” Organometallics, 2007, 26, 6184.
    16. M.-H. Hsu, R.-T. Chen, W.-S. Sheu and M. Shieh,* “Carbon Dioxide Fixation by an Unprecedented Hydroxo Lead-Chromium Carbonyl Complex: Synthesis, Reactivity, and Theoretical Calculations,” Inorg. Chem., 2006, 45, 6740.
    17. Y.-W. Lai, J.-J. Cherng, W.-S. Sheu, G.-A. Lee and M. Shieh,* “Novel Types of Organic S-Fe-CO Complexes: Reaction of [SFe3(CO)9]2- with Propargyl Bromide,” Organometallics, 2006, 25, 184.
    18. M. Shieh,* H.-S. Chen and Y.-W. Lai, “Reaction of the Tellurium-Capped Triiron Cluster [TeFe3(CO)9]2- with the Bifunctional Propargyl Bromide: Formation of a Series of Novel Organic Te-Fe-CO Complexes,” Organometallics, 2004, 23, 4018.
    19. M. Shieh,* S.-F. Lin, Y.-W. Guo, M.-H. Hsu and Y.-W. Lai, “New Strategy to Mixed-Group 6 Metal Carbonyl Telluride Complexes: Completion of the Trigonal Bipyramidal Clusters [Te2CrM2(CO)10]2- (M = Cr, Mo, W),” Organometallics, 2004, 23, 5182.
    20. M. Shieh,* R.-L. Chung, C.-H. Yu, M.-H Hsu, C.-H. Ho, S.-M. Peng and Y.-H. Liu, “The Unusual Paramagnetic Mixed-Metal Carbonyl Chalcogenide Clusters: [E2Cr2Fe(CO)10]2- (E = Te, Se),” Inorg. Chem., 2003, 42, 5477.
    21. M. Shieh,* L.-F. Ho, Y.-W. Guo, S.-F. Lin, Y.-C. Lin, S.-M. Peng and Y.-H. Liu, “Carbonylchromium Monotelluride Complexes [Et4N]2[Te{Cr(CO)5}n] (n = 2, 3): Two Important Intermediates,” Organometallics, 2003, 22, 5020.
    22. M. Shieh,* Y. Liou, M.-H. Hsu, R.-T. Chen, S.-J. Yeh, S.-M. Peng and G.-H. Lee, “A Unique Bismuth-Iron Chain Polymer Containing the ...-Bi-Fe-... Link: Formation and Structure of [n-BuBiFe(CO)4]¥,” Angew. Chem. Int. Ed. Engl., 2002, 41, 2384.
    23. M. Shieh,* J.-J. Cherng, Y.-W. Lai, S.-M. Peng and Y.-H. Liu, “Carbonylchromium Derivatives of Bismuth: New Syntheses and Relevance to C-O Activation,” Chem. Eur. J., 2002, 8, 4522.
    24. J.-J. Cherng, Y.-W. Lai, Y.-H. Liu, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis of Chromium Pentacarbonyl Dertives of Arsenic(V) and Antimony(V). Contrasting Chemical Reactivity with Organic Halogen Derivatives,” Inorg. Chem., 2001, 40, 1206.
    25. M. Shieh,* H.-S. Chen, H.-Y. Yang, S.-F. Lin and C.-H. Ueng, “Tellurium-Bridged Manganese Carbonyl Clusters: Synthesis and Structural Transformations of [Te4Mn3(CO)10]-, [Te2Mn3(CO)9]2-, [Te2Mn3(CO)9]-, and [Te2Mn4(CO)12]2-,” Chem. Eur. J., 2001, 7, 3152.
    26. M. Shieh,* L.-F. Ho, L.-F. Jang, C.-H. Ueng, S.-M. Peng and Y.-H. Liu, “First Selenium-Capped Carbonyltrichromium Complex [Se2Cr3(CO)10]2-: a Novel Cr3 Ring Cluster,” Chem. Commun., 2001, 1014.
    27. M. Shieh,* H.-S. Chen, H.-H Chi and C.-H. Ueng, “Synthesis of an Se-Bridged Triiron Acyl Cluster Complex and the Fischer-Type Carbene Complex Derived from It: Isolation of Rotation Isomers,” Inorg. Chem., 2000, 39, 5561.
    28. J.-J. Cherng, G.-H. Lee, S.-M. Peng, C.-H. Ueng and M. Shieh,* “Synthesis and Characterization of a New Series of Chromium-Group 15 Hydride Complexes [Et4N]2[H{Cr(CO)5}3]) (E = As, Sb),” Organometallics, 2000, 19, 213-215.
    29. M. Shieh,* H.-S. Chen, H.-Y. Yang and C.-H. Ueng, “[(TeMe2)Mn(CO)4(m5-Te)(m4-Te)Mn4(CO)12]-: A Pentacoordinate Bridging Tellurido Ligand in a Square- Pyramidal Geometry,” Angew. Chem., 1999, 111, 1339-1341; Angew. Chem. Int. Ed. Engl., 1999, 38, 1252-1254.
經歷一覽
服務機關 職稱 部門/系所 擔任職務 起迄年月
National Taiwan Normal UniversityDistinguished ProfessorDepartment of Chemistry 2011-02 ~
National Science Council ChemistryAdvisory Committee2009-01 ~ 2011-12
National Science Council Chemistry Research Promotion CenterAdvisory Committee2004-01 ~ 2005-12
National Taiwan Normal UniversityProfessorDepartment of ChemistryChairman2003-08 ~ 2006-07
Academia SinicaAdjunct Research FellowInstitute of Chemistry 2002-10 ~
National Science Council Inorganic DivisionPanel2000-01 ~ 2002-12
National Taiwan Normal UniversityProfessorDepartment of ChemistryProfessor1994-08 ~
National Taiwan Normal UniversityAssociate ProfessorDepartment of ChemistryAssociate Professor1989-08 ~ 1994-07
Texas A & M UniversityPostdoctoral Research AssociateDepartment of ChemistryResearch Associate1988-08 ~ 1989-07
National Taiwan Normal UniversityTeaching AssistantDepartment of ChemistryTeaching Assistant1982-08 ~ 1984-07
學歷一覽
學校名稱 國別 系所 學位 起迄年月
Rice UniversityU.S.ChemistryPh.D.1984-08 ~ 1988-06
National Taiwan Normal UniversityTaiwanChemistryB.S.1978-09 ~ 1982-06
Congratulations一覽
得獎年度 獎項名稱 頒獎單位
 
Off-campus Excellence一覽
得獎年度 獎項名稱 頒獎單位
2000A-level National Science Council Research AwardNational Science Council
1999A-level National Science Council Research AwardNational Science Council
1998A-level National Science Council Research AwardNational Science Council
1997A-level National Science Council Research AwardNational Science Council
1996A-level National Science Council Research AwardNational Science Council
1995A-level National Science Council Research AwardNational Science Council
1994A-level National Science Council Research AwardNational Science Council
1993A-level National Science Council Research AwardNational Science Council
1991A-level National Science Council Research AwardNational Science Council
web_use_log